Anion dependent self-assembly of a linear hexanuclear Yb(III) salen complex with enhanced near-infrared (NIR) luminescence properties.

TitleAnion dependent self-assembly of a linear hexanuclear Yb(III) salen complex with enhanced near-infrared (NIR) luminescence properties.
Publication TypeJournal Article
Year of Publication2013
AuthorsYang X, Oye MM, Jones RA, Huang S
JournalChemical communications (Cambridge, England)
Volume49
Issue83
Pagination9579-81
Date Published2013 Oct 25
Abstract

Reactions of H2salen (H2L, N,N'-ethylene bis(salicylideneimine)) with Yb(CF3SO3)3, Yb(OAc)34H2O and Yb(NO3)36H2O in MeOH–EtOH under reflux gave NIR luminescent complexes [Yb6L9(H2L)2] (1), [Yb3L3(HL)(OH)2] (2) and [Yb2L2(H2L)2(NO3)(MeOH)2]NO3 (3), respectively.

DOI10.1016/j.redox.2012.11.004
Alternate JournalChem. Commun. (Camb.)