Probing the C₆₀ triplet state coupling to nuclear spins inside and out.

TitleProbing the C₆₀ triplet state coupling to nuclear spins inside and out.
Publication TypeJournal Article
Year of Publication2013
AuthorsFilidou V, Mamone S, Simmons S, Karlen SD, Anderson HL, Kay CWM, Bagno A, Rastrelli F, Murata Y, Komatsu K, Lei X, Li Y, Turro NJ, Levitt MH, Morton JJL
JournalPhilosophical transactions. Series A, Mathematical, physical, and engineering sciences
Volume371
Issue1998
Pagination20120475
Date Published2013 Sep 13
Abstract

The photoexcitation of functionalized fullerenes to their paramagnetic triplet electronic state can be studied by pulsed electron paramagnetic resonance (EPR) spectroscopy, whereas the interactions of this state with the surrounding nuclear spins can be observed by a related technique: electron nuclear double resonance (ENDOR). In this study, we present EPR and ENDOR studies on a functionalized exohedral fullerene system, dimethyl[9-hydro (C60-Ih)[5,6]fulleren-1(9H)-yl]phosphonate (DMHFP), where the triplet electron spin has been used to hyperpolarize, couple and measure two nuclear spins. We go on to discuss the extension of these methods to study a new class of endohedral fullerenes filled with small molecules, such as H₂@C₆₀, and we relate the results to density functional calculations.

DOI10.1093/jxb/ert178
Alternate JournalPhilos Trans A Math Phys Eng Sci